Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.
نویسندگان
چکیده
NHC-stabilized 2-hydrophosphasilenes are obtained from 1,2-dihydro-2-chlorophosphasilanes as Si(iv) precursors by a NHC-assisted 1,2-elimination of HCl. The NHC-exchange of these compounds is demonstrated as a proof of donor acceptor bonding between NHC and the silicon centre of the "Si[double bond, length as m-dash]P" moiety. We have also explored the possibility of similar exchanges in NHC-stabilized Si2 and P2 compounds. Theoretical DFT calculations were performed to address the nature of Si-P bonding in the NHC-stabilized 2-hydrophosphasilenes.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 48 شماره
صفحات -
تاریخ انتشار 2016